Strategies to High-quality Nanomaterials
Aiming at state-of-the-art nanomaterials - in addition to the initial particle size - aspects such as size distribution, degree of agglomeration, colloidal stability, surface conditioning, redispersibility and biocompatibility are of major importance, too. Moreover, the crystallinity of as-prepared materials can be essential due to the fact that certain physical properties (e.g., pigment color, electron/ion conductivity, luminescence, magnetism, catalysis) are restricted to crystalline host lattices. To meet the above requirements, liquid-phase synthesis of nanomaterials is performed in the research team via the following methods:
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Synthesis in high-boiling alcohols (Polyol-mediated synthesis)
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Microwave-assisted synthesis in ionic liquids
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Microemulsion techniques
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Solvothermal / hydrothermal methods
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Spray-drying
Synthesis and characterization of nanomaterials, which have not been realized on the nanoscale till now, as well as the realization of novel compounds and morphologies are key-issues of our research activities. Furthermore, the relevant properties of nanoscale functional materials are investigated. This includes:
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Luminescent nanomaterials
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Nanoscale transparent conductive oxides
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Nanoscale catalysts/photocatalysts
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Nanoscale color pigments
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Nanoscale magnetic pigments
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Nanomaterials for medical application
Some typical nanomaterials are shown below. These examples are prepared via polyol-mediated synthesis (Figure 1), microemulsion techniques (Figure 2) and microwave-assisted synthesis in ionic liquids (Figure 3):
Figure 1: Nanomaterials prepared via the polyol-mediated Synthesis
Figure 2: Nanomaterials prepared via microemulsion techniques
Figure 3: Nanomaterials prepared via microwave-assisted synthesis in ionic liquids.
For more information see:
C. Feldmann*, Polyol-mediated Synthesis of Nanoscale Functional Materials, Adv. Funct. Mater. 2003, 13, 101–107.
D. H. M. Buchold, C. Feldmann*, Microemulsion Approach to Non-agglomerated and Crystalline Nanomaterials, Adv. Funct. Mater. 2008, 18, 1002–1011.
G. Bühler, C. Feldmann*, Microwave-assisted Synthesis of Luminescent LaPO4:Ce,Tb Nanocrystals in Ionic Liquids, Angew. Chem. Int. Ed. 2006, 45, 4864–4867.