Strategies to High-quality Nanomaterials

 

Aiming at state-of-the-art nanomaterials - in addition to the initial particle size - aspects such as size distribution, degree of agglomeration, colloidal stability, surface conditioning, redispersibility and biocompatibility are of major importance, too. Moreover, the crystallinity of as-prepared materials can be essential due to the fact that certain physical properties (e.g., pigment color, electron/ion conductivity, luminescence, magnetism, catalysis) are restricted to crystalline host lattices. To meet the above requirements, liquid-phase synthesis of nanomaterials is performed in the research team via the following methods:

  • Synthesis in high-boiling alcohols (Polyol-mediated synthesis)
  • Microwave-assisted synthesis in ionic liquids
  • Microemulsion techniques
  • Solvothermal / hydrothermal methods
  • Spray-drying

 

Synthesis and characterization of nanomaterials, which have not been realized on the nanoscale till now, as well as the realization of novel compounds and morphologies are key-issues of our research activities. Furthermore, the relevant properties of nanoscale functional materials are investigated. This includes:

  • Luminescent nanomaterials
  • Nanoscale transparent conductive oxides
  • Nanoscale catalysts/photocatalysts
  • Nanoscale color pigments
  • Nanoscale magnetic pigments
  • Nanomaterials for medical application

 

Some typical nanomaterials are shown below. These examples are prepared via polyol-mediated synthesis (Figure 1), microemulsion techniques (Figure 2) and microwave-assisted synthesis in ionic liquids (Figure 3):

 



Figure 1: Nanomaterials prepared via the polyol-mediated Synthesis

 


Figure 2: Nanomaterials prepared via microemulsion techniques

 


Figure 3: Nanomaterials prepared via microwave-assisted synthesis in ionic liquids.

 

For more information see:

C. Feldmann*, Polyol-mediated Synthesis of Nanoscale Functional Materials, Adv. Funct. Mater. 2003, 13, 101–107.

D. H. M. Buchold, C. Feldmann*, Microemulsion Approach to Non-agglomerated and Crystalline Nanomaterials, Adv. Funct. Mater. 2008, 18, 1002–1011.

G. Bühler, C. Feldmann*, Microwave-assisted Synthesis of Luminescent LaPO4:Ce,Tb Nanocrystals in Ionic Liquids, Angew. Chem. Int. Ed. 2006, 45, 4864–4867.